Journal article icon

Journal article

NUCLEAR MAGNETIC-RESONANCE SPECTRUM OF THE SODIUM ANION IN SODIUM-N,N-DIETHYLACETAMIDE SOLUTIONS - THE SODIDE ION IN THE PRESENCE OF A CARBONYL MOIETY

Abstract:
We report the 23Na NMR spectrum of the sodium anion, Na-, in fluid solutions of sodium in N,N-diethylacetamide (DEA); even in the presence of the (amide) carbonyl moiety, the sodide ion exists in this solvent as a stable, gaslike centrosymmetric species with two valence electrons residing in an unperturbed 3s orbital on sodium. Proton (1H) and carbon-13 (13C) NMR spectra are consistent with this picture, with solvent nuclei showing only minor shifts from the pure DEA situation. © 1983 American Chemical Society.
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1021/j100245a010

Authors


Journal:
JOURNAL OF PHYSICAL CHEMISTRY More from this journal
Volume:
87
Issue:
22
Pages:
4362-4363
Publication date:
1983-01-01
DOI:
EISSN:
1541-5740
ISSN:
0022-3654
Language:
English
Pubs id:
pubs:46368
UUID:
uuid:0569f7ed-f65b-4f8c-a9f9-9d9ca85eb2cf
Local pid:
pubs:46368
Source identifiers:
46368
Deposit date:
2012-12-19

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP