Journal article
Cationic terminal borylene complexes: structure/bonding analysis and [4+1] cycloaddition reactivity of a BN vinylidene analogue.
- Abstract:
- (Chemical Equation Presented) Charge changes everything: The cationic terminal aminoborylene complex [CpFe(CO)2(BNCy2)] +[BArF4]- (1, Cy = cyclohexyl, ArF = 3,5-(CF3)2C6H3; Fe orange, B green, N blue, O red, C gray) was structurally characterized. DFT studies (see HOMO-2) indicate delocalized π bonding along the linear Fe-B-N framework and significant Fe-B and B-N multiple-bond character. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA.
- Publication status:
- Published
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- Publisher copy:
- 10.1002/anie.200602162
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Bibliographic Details
- Journal:
- Angewandte Chemie (International ed. in English)
- Volume:
- 45
- Issue:
- 37
- Pages:
- 6118-6122
- Publication date:
- 2006-09-01
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- Source identifiers:
-
46044
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:46044
- UUID:
-
uuid:0508e3cb-71cc-4d50-9c20-f3d01a816108
- Local pid:
- pubs:46044
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2006
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