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Cationic terminal borylene complexes: structure/bonding analysis and [4+1] cycloaddition reactivity of a BN vinylidene analogue.

Abstract:
(Chemical Equation Presented) Charge changes everything: The cationic terminal aminoborylene complex [CpFe(CO)2(BNCy2)] +[BArF4]- (1, Cy = cyclohexyl, ArF = 3,5-(CF3)2C6H3; Fe orange, B green, N blue, O red, C gray) was structurally characterized. DFT studies (see HOMO-2) indicate delocalized π bonding along the linear Fe-B-N framework and significant Fe-B and B-N multiple-bond character. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA.
Publication status:
Published

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Publisher copy:
10.1002/anie.200602162

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Journal:
Angewandte Chemie (International ed. in English)
Volume:
45
Issue:
37
Pages:
6118-6122
Publication date:
2006-09-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Source identifiers:
46044
Language:
English
Keywords:
Pubs id:
pubs:46044
UUID:
uuid:0508e3cb-71cc-4d50-9c20-f3d01a816108
Local pid:
pubs:46044
Deposit date:
2012-12-19

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