Journal article

Cation-induced molecular motion of spring-like [2]catenanes

Abstract:: The syntheses and cation recognition studies of two novel heteroditopic [2]catenanes that are capable of reversible rotary motion are described. Prepared by chloride anion templation, both catenanes possess a calixdiquinone unit able to bind Na+, K+, NH4+ and Ba2+ cations. Following characterization of thesalts of both catenanes by NMR, mass spectrometry and crystal structure determination, hexafluorophosphate salts were investigated for their behaviour upon addition of cations. Ba2+ complexation caused a partial intra-ring rotation of the two macrocycles in both species, which was reversed upon addition of the sequestering SO42- anion. © The Royal Society of Chemistry 2011.

Publication status:: Published

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APA Style

Leontiev, A., Serpell, C., White, N., & Beer, P. (2011). Cation-induced molecular motion of spring-like [2]catenanes. CHEMICAL SCIENCE, 2(5), 922–927.

MLA Style

Leontiev, A, et al. “Cation-Induced Molecular Motion of Spring-like [2]Catenanes.” CHEMICAL SCIENCE, vol. 2, no. 5, 2011, pp. 922–27.

Chicago Style

Leontiev, A, C Serpell, N White, and P Beer. 2011. “Cation-Induced Molecular Motion of Spring-like [2]Catenanes.” CHEMICAL SCIENCE 2 (5): 922–27.
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Publisher copy:: 10.1039/c1sc00034a

Authors

+ Leontiev, A More by this author

Role:: Author

+ Serpell, C More by this author

Role:: Author

+ White, N More by this author

Role:: Author

+ Beer, P More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

Journal:: CHEMICAL SCIENCE More from this journal
Volume:: 2
Issue:: 5
Pages:: 922-927
Publication date:: 2011-01-01
DOI:: 10.1039/c1sc00034a
EISSN:: 2041-6539
ISSN:: 2041-6520

Language:: English
Pubs id:: pubs:146743
UUID:: uuid:04fe70ba-7f7e-415e-b65c-4f9a131cd558
Local pid:: pubs:146743
Source identifiers:: 146743
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_04fe70ba7f7e415eb65c4f9a131cd558

Terms of use

Copyright date:: 2011

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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