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Measuring the solubility of benzoic acid in room temperature ionic liquids using chronoamperometric techniques

Abstract:

The electrochemical reduction of benzoic acid (BZA) has been studied at platinum micro-electrodes (10 and 2 |u̧m diameters) in acetonitrile (MeCN) and six room temperature ionic liquids (RTILs): [C2mim][NTf 2], [C4mim][NTf2], [C4mpyrr] [NTf2], [C4mim][BF4], [C4mim] [NO3] and [C4mim][PF6] (where [C nmim]+ = 1-alkyl-3-methylimidazolium, [NTf2]- = bis(trifluoromethylsulphonyl)imide, [C4mpyrr]+ = N-butyl-N-methylpyrrolidinium, [BF4]- = tetrafluoroborate, [NO 3]- = nitrate and [PF6]- = hexafluorop...

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Publication status:
Published

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Publisher copy:
10.1002/poc.1428

Authors


Silvester, DS More by this author
Streeter, I More by this author
Hardacre, C More by this author
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Journal:
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
Volume:
22
Issue:
1
Pages:
69-76
Publication date:
2009-01-05
DOI:
EISSN:
1099-1395
ISSN:
0894-3230
URN:
uuid:04e08f72-95e1-4d1d-a500-19ed651328e6
Source identifiers:
40997
Local pid:
pubs:40997

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