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La2SrCr2O7F2: A Ruddlesden-Popper oxyfluoride containing octahedrally coordinated Cr(4+) centers

Abstract:

The low-temperature fluorination of the n = 2 Ruddlesden-Popper phase La2SrCr2O7 yields La2SrCr2O7F2 via a topochemical fluorine insertion reaction. The structure-conserving nature of the fluorination reaction means that the chromium centers of the initial oxide phase retain an octahedral coordination environment in the fluorinated product, resulting in a material containing an extended array of apex-linked Cr(4+)O6 units. Typically materials containing networks of octahedrally coordinated Cr...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1021/acs.inorgchem.6b00114

Authors


Lancaster, T More by this author
More by this author
Department:
Oxford, MPLS, Physics, Condensed Matter Physics
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Engineering and Physical Sciences Research Council More from this funder
Publisher:
American Chemical Society Publisher's website
Journal:
Inorganic Chemistry Journal website
Volume:
55
Issue:
6
Pages:
3169–3174
Publication date:
2016-03-09
Acceptance date:
2016-03-01
DOI:
ISSN:
0020-1669 and 1520-510X
Pubs id:
pubs:607188
URN:
uri:04d579b3-5d98-4975-9bf7-1d649eb04ef8
UUID:
uuid:04d579b3-5d98-4975-9bf7-1d649eb04ef8
Local pid:
pubs:607188

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