- Abstract:
-
Salt metathesis reactions between ethylenediamine (en) solutions of the K(3)E(7) (E = P, As) Zintl phases and post-transition metal halides (InCl(3), TlCl, SnI(2) and PbI(2)) have yielded a family of novel heteroatomic cluster anions, [In(E(7))(2)](3-), [TlE(7)](2-) and [E'E(15)](3-) (E' = Sn, Pb; E = P, As). Several of these new species have been characterized by single-crystal X-ray diffraction as salts of sequestered potassium cations in [K(2,2,2-crypt)](3)[In(P(7))(2)]·3.5py (1), [K(2,2,2...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/c0dt00918k
-
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- Journal:
- Dalton transactions (Cambridge, England : 2003)
- Volume:
- 40
- Issue:
- 3
- Pages:
- 735-745
- Publication date:
- 2011-01-05
- DOI:
- EISSN:
-
1477-9234
- ISSN:
-
1477-9226
- URN:
-
uuid:0490c511-122b-42fd-91e8-df62c407a520
- Source identifiers:
-
103639
- Local pid:
- pubs:103639
- Language:
- English
- Copyright date:
- 2011
Journal article
A versatile salt-metathesis route to heteroatomic clusters derived from phosphorus and arsenic Zintl anions.
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