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A versatile salt-metathesis route to heteroatomic clusters derived from phosphorus and arsenic Zintl anions.

Abstract:

Salt metathesis reactions between ethylenediamine (en) solutions of the K(3)E(7) (E = P, As) Zintl phases and post-transition metal halides (InCl(3), TlCl, SnI(2) and PbI(2)) have yielded a family of novel heteroatomic cluster anions, [In(E(7))(2)](3-), [TlE(7)](2-) and [E'E(15)](3-) (E' = Sn, Pb; E = P, As). Several of these new species have been characterized by single-crystal X-ray diffraction as salts of sequestered potassium cations in [K(2,2,2-crypt)](3)[In(P(7))(2)]·3.5py (1), [K(2,2,2...

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Publication status:
Published

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Publisher copy:
10.1039/c0dt00918k

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Dalton transactions (Cambridge, England : 2003)
Volume:
40
Issue:
3
Pages:
735-745
Publication date:
2011-01-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:0490c511-122b-42fd-91e8-df62c407a520
Source identifiers:
103639
Local pid:
pubs:103639
Language:
English

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