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Ion pair formation between the electrogenerated 2,3-dichloro-5,6-dicyano-1,4-benzoquinone dianion and the sodium ion at platinum surfaces

Abstract:

The electrochemical reduction at platinum electrodes of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) in the presence of Na+ in acetonitrile solution was studied using various electrochemical measurements under conditions with significant mass transport, namely channel flow- and sono-voltammetries. In channel electrode voltammetry, the presence of Na+ was observed to change the voltammetric response from that of pure DDQ alone. In particular, at potentials corresponding, in the absence of N...

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Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
451
Issue:
1-2
Pages:
193-201
Publication date:
1998-07-01
DOI:
ISSN:
0022-0728
Language:
English
Keywords:
UUID:
uuid:0485e2f6-da6d-4dc8-bace-467706010229
Local pid:
pubs:36543
Source identifiers:
36543
Deposit date:
2012-12-19

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