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Probing Conformational Strain in Multinuclear Lewis Acids: Synthesis, Spectroscopic and Structural Characterization of the Dinuclear Ferroceneboronic Ester (eta(5)-C5H5)Fe(eta(5)-C5H4)BO2C5H8O2B(eta(5)-C5H4)Fe(eta(5)-C5H5)

Abstract:

The facile linking of ferrocene units into multinuclear frameworks via boronic ester condensation chemistry is demonstrated through the synthesis of (η5-C5H5)Fe(η5-C 5H4)BO2C5H8O 2B(η5-C5H4)Fe(η5- C5H5), which has been characterized by standard spectroscopic techniques and its structure (as the chloroform solvate) determined crystallographically. The crystal structure reveals the following properties: monoclinic, space group P21/n with a = 22.5093(3), b = 5.8951(3), c = 22.9770(5) Å, β = 119....

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Publication status:
Published

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Publisher copy:
10.1007/s10870-009-9624-y

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More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
Volume:
40
Issue:
2
Pages:
156-159
Publication date:
2010-02-05
DOI:
EISSN:
1572-8854
ISSN:
1074-1542
URN:
uuid:04799b3d-ca91-413e-8625-cbbd2928d053
Source identifiers:
48518
Local pid:
pubs:48518

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