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The intercalation of bicyclic and tricyclic carboxylates into layered double hydroxides

Abstract:

Twenty-four nanocomposites built from layered double hydroxides and bicyclic and tricyclic carboxylates have been synthesised for the first time. Eight carboxylates were successfully intercalated into [LiAl2(OH) 6]Cl·yH2O, [Ca2Al(OH) 6]NO3·yH2O, and [Mg2Al(OH) 6]NO3·yH2O, and the products fully characterised. Guest species incorporated include 1-adamantane carboxylate (1-AC) and 5-norbornene-2-endo-3-exo-dicarboxylate. In some cases, carbonate anions were co-intercalated with the organic gues...

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Publication status:
Published

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Publisher copy:
10.1016/j.jssc.2010.09.036

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF SOLID STATE CHEMISTRY More from this journal
Volume:
183
Issue:
12
Pages:
2877-2885
Publication date:
2010-12-01
DOI:
EISSN:
1095-726X
ISSN:
0022-4596
Language:
English
Keywords:
Pubs id:
pubs:118879
UUID:
uuid:04681d59-f3d7-43fc-a2c8-d40f843eeec8
Local pid:
pubs:118879
Source identifiers:
118879
Deposit date:
2012-12-19

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