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Dimethylamine borane dehydrogenation chemistry: syntheses, X-ray and neutron diffraction studies of 18-electron aminoborane and 14-electron aminoboryl complexes.

Abstract:
The reactions of Me(2)NH·BH(3) with cationic Rh(III) and Ir(III) complexes have been shown to generate the 18-electron aminoborane adduct [Ir(IMes)(2)(H)(2){κ(2)-H(2)BNMe(2))](+) and the remarkable 14-electron aminoboryl complex [Rh(IMes)(2)(H)-{B(H)NMe(2))](+). Neutron diffraction studies have been used for the first time to define H-atom locations in metal complexes of this type formed under catalytic conditions.
Publication status:
Published

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Publisher copy:
10.1039/c2cc33361a

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Journal:
Chemical Communications
Volume:
48
Issue:
65
Pages:
8096-8098
Publication date:
2012-08-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Source identifiers:
342295
Language:
English
Pubs id:
pubs:342295
UUID:
uuid:045e9258-4dd3-4c2f-992a-edd52f60d480
Local pid:
pubs:342295
Deposit date:
2012-12-19

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