Journal article
Dimethylamine borane dehydrogenation chemistry: syntheses, X-ray and neutron diffraction studies of 18-electron aminoborane and 14-electron aminoboryl complexes.
- Abstract:
- The reactions of Me(2)NH·BH(3) with cationic Rh(III) and Ir(III) complexes have been shown to generate the 18-electron aminoborane adduct [Ir(IMes)(2)(H)(2){κ(2)-H(2)BNMe(2))](+) and the remarkable 14-electron aminoboryl complex [Rh(IMes)(2)(H)-{B(H)NMe(2))](+). Neutron diffraction studies have been used for the first time to define H-atom locations in metal complexes of this type formed under catalytic conditions.
- Publication status:
- Published
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- Publisher copy:
- 10.1039/c2cc33361a
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Authors
Bibliographic Details
- Journal:
- Chemical Communications
- Volume:
- 48
- Issue:
- 65
- Pages:
- 8096-8098
- Publication date:
- 2012-08-01
- DOI:
- EISSN:
-
1364-548X
- ISSN:
-
1359-7345
- Source identifiers:
-
342295
Item Description
- Language:
- English
- Pubs id:
-
pubs:342295
- UUID:
-
uuid:045e9258-4dd3-4c2f-992a-edd52f60d480
- Local pid:
- pubs:342295
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2012
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