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Direct detection and measurement of electron relays in a multicentered enzyme: Voltammetry of electrode-surface films of E-coli fumarate reductase, an iron-sulfur flavoprotein

Abstract:: Intramolecular electron relays operating in a multicentered enzyme are revealed by protein film voltammetry. The membrane-extrinsic catalytic domain of E. coli fumarate reductase (FrdAB) adsorbs to electroactive monolayer coverage at a rotating pyrolytic graphite edge electrode, giving characteristic voltammetric signals that are resolved and assigned to redox-active sites. At pH 7.3 (2°C), signals attributable to Centers 1 ([2Fe-2S) and 3 ([3Fe-4S]) and FAD are envelop together around -50 mV...
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Publication status:: Published

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APA Style

Heering, H., Weiner, J., & Armstrong, F. (1997). Direct detection and measurement of electron relays in a multicentered enzyme: Voltammetry of electrode-surface films of E-coli fumarate reductase, an iron-sulfur flavoprotein. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 119(48), 11628–11638.

MLA Style

Heering, H., et al. “Direct Detection and Measurement of Electron Relays in a Multicentered Enzyme: Voltammetry of Electrode-Surface Films of E-Coli Fumarate Reductase, an Iron-Sulfur Flavoprotein.” JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 119, no. 48, 1997, pp. 11628–38.

Chicago Style

Heering, H, J Weiner, and F Armstrong. 1997. “Direct Detection and Measurement of Electron Relays in a Multicentered Enzyme: Voltammetry of Electrode-Surface Films of E-Coli Fumarate Reductase, an Iron-Sulfur Flavoprotein.” JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 119 (48): 11628–38.
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Publisher copy:: 10.1021/ja9723242

Authors

+ Heering, H More by this author

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Author

+ Weiner, J More by this author

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Author

+ Armstrong, F More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Chemistry

Sub department:

Inorganic Chemistry

Role:

Author

Bibliographic Details

Journal:: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume:: 119
Issue:: 48
Pages:: 11628-11638
Publication date:: 1997-12-03
DOI:: 10.1021/ja9723242
EISSN:: 1520-5126
ISSN:: 0002-7863

Item Description

Language:: English
Pubs id:: pubs:45720
UUID:: uuid:040c0a83-46e2-4dfd-a428-f73c2c46571c
Local pid:: pubs:45720
Source identifiers:: 45720
Deposit date:: 2013-11-16

Terms of use

Copyright date:: 1997

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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