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Electrocatalytic reduction of alkyl iodides in tetrahydrofuran at silver electrodes

Abstract:

Recent interest in the electrocatalytic activity of silver towards the reduction of alkyl iodides haş led us to investigate whether the effect is observed in tetrahydrofuran (THF) at room temperature. Using platinum electrodes in THF for the reduction of alkyl halides at 298 K has been hampered by the solvent window, which 'obscures' the voltammetric signals of interest. In order to overcome these problems, voltammetry has been performed at low temperature and was shown to extend the voltamme...

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Publication status:
Published

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Publisher copy:
10.1002/poc.1133

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
Volume:
20
Issue:
2
Pages:
115-121
Publication date:
2007-02-05
DOI:
EISSN:
1099-1395
ISSN:
0894-3230
URN:
uuid:03da3185-27c8-42f6-8101-d28cb6e5a4d0
Source identifiers:
40314
Local pid:
pubs:40314

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