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Homoleptic cobalt and copper phenolate A2[M(OAr)4] compounds: the effect of phenoxide fluorination.

Abstract:

Two series of homoleptic phenolate complexes with fluorinated aryloxide ligands A2[M(OAr)4] with M=Co2+ or Cu2+, OAr-=(OC6F5)- (OArF) or [3,5-OC6H3(CF3)2]- (OAr'), A+=K (18-crown-6)+, Tl+, Ph4P+, Et3HN+, or Me4N+ have been synthesized. Two related complexes with nonfluorinated phenoxide ligands have been synthesized and studied in comparison to the fluorinated aryloxides demonstrating the dramatic structural changes effected by modification of OPh to OAr(F). The compounds [K(18-crown-6)]2[Cu(...

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Publisher copy:
10.1021/ic0493954

Authors


Buzzeo, MC More by this author
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Journal:
Inorganic chemistry
Volume:
43
Issue:
24
Pages:
7709-7725
Publication date:
2004-11-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:03c79798-a121-45e2-b764-9330c3085a8d
Source identifiers:
58738
Local pid:
pubs:58738
Language:
English

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