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Charge-Carrier Dynamics and Mobilities in Formamidinium Lead Mixed-Halide Perovskites

Abstract:
The mixed-halide perovskite FAPb(BryI1–y)3 is attractive for color-tunable and tandem solar cells. Bimolecular and Auger charge-carrier recombination rate constants strongly correlate with the Br content, y, suggesting a link with electronic structure. FAPbBr3 and FAPbI3 exhibit charge-carrier mobilities of 14 and 27 cm2 V−1 s−1 and diffusion lengths exceeding 1 μm, while mobilities across the mixed Br/I system depend on crystalline phase disorder.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/adma.201502969

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author
More from this funder
Funding agency for:
Eperon, G
Grant:
CASE studentship
More from this funder
Funding agency for:
Eperon, G
Grant:
CASE studentship
More from this funder
Funding agency for:
Rehman, W
Grant:
Doctoral Scholarship
Publisher:
Wiley Publisher's website
Journal:
Advanced Materials Journal website
Pages:
n/a-n/a
Publication date:
2015-09-24
DOI:
EISSN:
1521-4095
ISSN:
0935-9648
Pubs id:
pubs:580280
UUID:
uuid:03c72041-954f-475c-980e-2e6d200b9063
Local pid:
pubs:580280
Source identifiers:
580280
Deposit date:
2015-12-20

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