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The chemistry of nitrogen oxides on small size-selected cobalt clusters, Co(n) (+).

Abstract:

Fourier transform ion cyclotron resonance mass spectrometry has been employed to study the reactions of gas-phase cationic cobalt clusters, Co(n) (+) (n=4-30), with nitric oxide, NO, and nitrous oxide, N(2)O, under single collision conditions. Isolation of the initial cluster permits detailed investigation of fragmentation channels which characterize the reactions of all but the largest clusters studied. In reaction with N(2)O, most clusters generate the monoxides Co(n)O(+) without fragmentat...

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Publication status:
Published

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Publisher copy:
10.1063/1.3075583

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Journal:
The Journal of chemical physics
Volume:
130
Issue:
6
Pages:
064305
Publication date:
2009-02-05
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
URN:
uuid:03c6372a-f6b8-4e81-977a-45de6d3b3d54
Source identifiers:
41117
Local pid:
pubs:41117

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