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Vibrational relaxation of NO (v=1-16) in collisions with O-2 studied by time resolved Fourier transform infrared emission

Abstract:
Rates of vibrational quenching of NO (v = 1-16) in collisions with O2 have been measured at 295 K. NO(v) was formed both by the O(1D) + N2O reaction and the 193 nm photolysis of NO2, and time resolved FT-IR emission was used to follow the behaviour of the vibrationally excited species. Rate constants were found to peak close to resonance for the single quantum exchange process between NO and O2. © 2006 Elsevier B.V. All rights reserved.
Publication status:
Published

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Publisher copy:
10.1016/j.cplett.2006.05.027

Authors

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author


Journal:
CHEMICAL PHYSICS LETTERS More from this journal
Volume:
425
Issue:
4-6
Pages:
216-220
Publication date:
2006-07-10
DOI:
ISSN:
0009-2614


Language:
English
Pubs id:
pubs:40038
UUID:
uuid:0382ddb5-b7aa-47d0-97ff-e4633679dd58
Local pid:
pubs:40038
Source identifiers:
40038
Deposit date:
2012-12-19
ARK identifier:

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