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HETERO-BI-METALLIC AND TRI-METALLIC COMPLEXES CONTAINING BOTH ELECTRON RELEASING AND ELECTRON ACCEPTING REDOX CENTERS

Abstract:: The new complexes [M(η5-C5H4CH2O)2Mo(NO)L{black star}]; M = Fe or Ru and L{black star} = (hydro)tris(3,5-dimethylpyrazolyl)borate, which contain a chelating metallocene ligand, have been prepared and characterised along with the related trimetallic complex [{Fe(η5-C5H5)(η5-C5H4CH2O)}2Mo(NO)L{black star}]. Their electrochemical properties are reported, and the reduction potentials for the {Mo(NO)}4+ redox centre in the chelated species are 100 mV more anodic than for that in the trimetallic non-chelated complex. © 1987.

Publication status:: Published

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APA Style

Beer, P., Jones, C., Mccleverty, J., & Sidebotham, R. (1987). HETERO-BI-METALLIC AND TRI-METALLIC COMPLEXES CONTAINING BOTH ELECTRON RELEASING AND ELECTRON ACCEPTING REDOX CENTERS. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 325(1-2), C19–C22.

MLA Style

Beer, P., et al. “HETERO-BI-METALLIC AND TRI-METALLIC COMPLEXES CONTAINING BOTH ELECTRON RELEASING AND ELECTRON ACCEPTING REDOX CENTERS.” JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 325, no. 1-2, 1987, pp. C19–C22.

Chicago Style

Beer, P, C Jones, J Mccleverty, and R Sidebotham. 1987. “HETERO-BI-METALLIC AND TRI-METALLIC COMPLEXES CONTAINING BOTH ELECTRON RELEASING AND ELECTRON ACCEPTING REDOX CENTERS.” JOURNAL OF ORGANOMETALLIC CHEMISTRY 325 (1-2): C19–C22.
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Publisher copy:: 10.1016/0022-328X(87)80415-1

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+ Beer, P More by this author

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+ Jones, C More by this author

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+ Mccleverty, J More by this author

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+ Sidebotham, R More by this author

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Bibliographic Details

Journal:: JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume:: 325
Issue:: 1-2
Pages:: C19-C22
Publication date:: 1987-05-12
DOI:: 10.1016/0022-328X(87)80415-1
ISSN:: 0022-328X

Item Description

Language:: English
Pubs id:: pubs:46117
UUID:: uuid:037d84ba-55a9-4a54-a559-f905044ff88a
Local pid:: pubs:46117
Source identifiers:: 46117
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 1987

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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