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Luminescence from neptunyl(VI) species in solution.

Abstract:
The luminescence from the neptunyl(VI) ion and its polyoxometallate complexes has been investigated in solution for the first time. Emission occurs in the near-IR and is quenched effectively by O-H oscillators in the hydrated ion. The polyoxometallate complexes exclude solvent from the neptunyl coordination sphere and have much more intense and longer-lived emission spectra. Copyright © 2007 American Chemical Society.
Publication status:
Published

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Publisher copy:
10.1021/ja068522n

Authors


Talbot-Eeckelaers, C More by this author
Copping, R More by this author
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Journal:
Journal of the American Chemical Society
Volume:
129
Issue:
9
Pages:
2442-2443
Publication date:
2007-03-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:03676288-8e24-4cbf-8465-4bd54aa676b0
Source identifiers:
33757
Local pid:
pubs:33757
Language:
English

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