Journal article
Luminescence from neptunyl(VI) species in solution.
- Abstract:
- The luminescence from the neptunyl(VI) ion and its polyoxometallate complexes has been investigated in solution for the first time. Emission occurs in the near-IR and is quenched effectively by O-H oscillators in the hydrated ion. The polyoxometallate complexes exclude solvent from the neptunyl coordination sphere and have much more intense and longer-lived emission spectra. Copyright © 2007 American Chemical Society.
- Publication status:
- Published
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- Publisher copy:
- 10.1021/ja068522n
Authors
- Journal:
- Journal of the American Chemical Society More from this journal
- Volume:
- 129
- Issue:
- 9
- Pages:
- 2442-2443
- Publication date:
- 2007-03-01
- DOI:
- EISSN:
-
1520-5126
- ISSN:
-
0002-7863
- Language:
-
English
- Pubs id:
-
pubs:33757
- UUID:
-
uuid:03676288-8e24-4cbf-8465-4bd54aa676b0
- Local pid:
-
pubs:33757
- Source identifiers:
-
33757
- Deposit date:
-
2012-12-19
- ARK identifier:
Terms of use
- Copyright date:
- 2007
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