Journal article
Synthesis and characterization of amidinate-iron(I) complexes: analogies with beta-diketiminate chemistry.
- Abstract:
-
The synthesis and characterization of amidinate-iron(I) complexes and its reactivity towards dinitrogen and carbon monoxide was reported. It is found that one complex is formed by the irreversible displacement of neutral N2 from the other complex upon its treatment with benzene. The differences in the reactivity of two complexes towards arene solvents is due to the ability of the Piso ion ligand to vary its coordination mode between N,N' and N,arene chelating. The smaller cone angle of the Pi...
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- Publication status:
- Published
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- Publisher copy:
- 10.1002/chem.200801071
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Bibliographic Details
- Journal:
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Volume:
- 14
- Issue:
- 28
- Pages:
- 8477-8480
- Publication date:
- 2008-01-01
- DOI:
- EISSN:
-
1521-3765
- ISSN:
-
0947-6539
- Source identifiers:
-
40903
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:40903
- UUID:
-
uuid:035b3328-91cb-4634-9c22-2903ca11b175
- Local pid:
- pubs:40903
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2008
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