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Synthesis and characterization of amidinate-iron(I) complexes: analogies with beta-diketiminate chemistry.

Abstract:

The synthesis and characterization of amidinate-iron(I) complexes and its reactivity towards dinitrogen and carbon monoxide was reported. It is found that one complex is formed by the irreversible displacement of neutral N2 from the other complex upon its treatment with benzene. The differences in the reactivity of two complexes towards arene solvents is due to the ability of the Piso ion ligand to vary its coordination mode between N,N' and N,arene chelating. The smaller cone angle of the Pi...

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Publication status:
Published

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Publisher copy:
10.1002/chem.200801071

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Chemistry (Weinheim an der Bergstrasse, Germany)
Volume:
14
Issue:
28
Pages:
8477-8480
Publication date:
2008-01-01
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
Source identifiers:
40903
Language:
English
Keywords:
Pubs id:
pubs:40903
UUID:
uuid:035b3328-91cb-4634-9c22-2903ca11b175
Local pid:
pubs:40903
Deposit date:
2012-12-19

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