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Strontium vanadium oxide-hydrides: "square-planar" two-electron phases.

Abstract:

A series of strontium vanadium oxide-hydride phases prepared by utilizing a low-temperature synthesis strategy in which oxide ions in Sr(n+1)V(n)O(3n+1) (n=∞, 1, 2) phases are topochemically replaced by hydride ions to form SrVO2H, Sr2VO3H, and Sr3V2O5H2, respectively. These new phases contain sheets or chains of apex-linked V(3+)O4 squares stacked with SrH layers/chains, such that the n=∞ member, SrVO2H, can be considered to be analogous to "infinite-layer" phases, such as Sr(1-x)Ca(x)CuO2 (...

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Publication status:
Published

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Publisher copy:
10.1002/anie.201403536

Authors


Denis Romero, F More by this author
Möller, JS More by this author
Foronda, F More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Physics, Condensed Matter Physics
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Publisher:
Wiley-VCH Verlag
Journal:
Angewandte Chemie (International ed. in English)
Volume:
53
Issue:
29
Pages:
7556-7559
Publication date:
2014-07-05
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:03356d79-2406-4537-bcd2-6a28c72e39e6
Source identifiers:
471088
Local pid:
pubs:471088

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