- Abstract:
-
A series of strontium vanadium oxide-hydride phases prepared by utilizing a low-temperature synthesis strategy in which oxide ions in Sr(n+1)V(n)O(3n+1) (n=∞, 1, 2) phases are topochemically replaced by hydride ions to form SrVO2H, Sr2VO3H, and Sr3V2O5H2, respectively. These new phases contain sheets or chains of apex-linked V(3+)O4 squares stacked with SrH layers/chains, such that the n=∞ member, SrVO2H, can be considered to be analogous to "infinite-layer" phases, such as Sr(1-x)Ca(x)CuO2 (...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1002/anie.201403536
-
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- Publisher:
- Wiley-VCH Verlag
- Journal:
- Angewandte Chemie (International ed. in English)
- Volume:
- 53
- Issue:
- 29
- Pages:
- 7556-7559
- Publication date:
- 2014-07-05
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- URN:
-
uuid:03356d79-2406-4537-bcd2-6a28c72e39e6
- Source identifiers:
-
471088
- Local pid:
- pubs:471088
- Language:
- English
- Keywords:
- Copyright date:
- 2014
Journal article
Strontium vanadium oxide-hydrides: "square-planar" two-electron phases.
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