Journal article
A new conducting ternary nitride: NaxTa3N5 (0<=x<=1.4)
- Abstract:
-
Topotactic insertion of sodium into the channel structure of Ta3N5has been accomplished by the reaction between Na and Ta3N5at temperatures between 450 and 600°C in sealed Ni tubes. The limiting stoichiometry of NaxTa3N5obtained isx≈1.4. The structure of Na1.0Ta3N5has been refined using Rietveld full-profile refinement of X-ray powder diffraction data using the Ta3N5structure as the starting model. The space group remainsCmcm(No. 63) with parametersa=3.995(1),b=10.197(2), andc=10.331(2) Å. Th...
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- Publication status:
- Published
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- Publisher copy:
- 10.1006/jssc.1997.7481
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Authors
Bibliographic Details
- Journal:
- JOURNAL OF SOLID STATE CHEMISTRY
- Volume:
- 132
- Issue:
- 2
- Pages:
- 394-398
- Publication date:
- 1997-09-05
- DOI:
- ISSN:
-
0022-4596
- URN:
-
uuid:02e13cbd-eabb-48f4-b183-fdee0eaa2ce6
- Source identifiers:
-
46746
- Local pid:
- pubs:46746
Item Description
- Language:
- English
Terms of use
- Copyright date:
- 1997
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