Journal article icon

Journal article

A porphyrin fused to four anthracenes.

Abstract:
We have synthesized a fused tetraanthracenylporphyrin by oxidation of a meso-anthracenyl nickel(II) porphyrin with FeCl(3). This compound exhibits an intense red-shifted absorption spectrum (λ(max) = 1417 nm; ε = 1.2 × 10(5) M(-1) cm(-1)) and a small electrochemical HOMO-LUMO gap (0.61 eV). The crystal structure shows that it forms π-stacked dimers with a short Ni···Ni distance (3.32 Å).
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1021/ja109671f

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
Journal of the American Chemical Society
Volume:
133
Issue:
1
Pages:
30-31
Publication date:
2011-01-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Source identifiers:
107009
Language:
English
Pubs id:
pubs:107009
UUID:
uuid:028ae4c8-ff30-42fb-a0c3-00906a91cbb9
Local pid:
pubs:107009
Deposit date:
2012-12-19

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP