Journal article
A porphyrin fused to four anthracenes.
- Abstract:
- We have synthesized a fused tetraanthracenylporphyrin by oxidation of a meso-anthracenyl nickel(II) porphyrin with FeCl(3). This compound exhibits an intense red-shifted absorption spectrum (λ(max) = 1417 nm; ε = 1.2 × 10(5) M(-1) cm(-1)) and a small electrochemical HOMO-LUMO gap (0.61 eV). The crystal structure shows that it forms π-stacked dimers with a short Ni···Ni distance (3.32 Å).
- Publication status:
- Published
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Bibliographic Details
- Journal:
- Journal of the American Chemical Society
- Volume:
- 133
- Issue:
- 1
- Pages:
- 30-31
- Publication date:
- 2011-01-01
- DOI:
- EISSN:
-
1520-5126
- ISSN:
-
0002-7863
- Source identifiers:
-
107009
Item Description
- Language:
- English
- Pubs id:
-
pubs:107009
- UUID:
-
uuid:028ae4c8-ff30-42fb-a0c3-00906a91cbb9
- Local pid:
- pubs:107009
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2011
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