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THE DISSOLUTION OF ICELAND SPAR CRYSTALS - THE EFFECT OF SURFACE-MORPHOLOGY

Abstract:
The effect of surface morphology on the dissolution rate of Iceland Spar crystals has been examined by a rotating disk method. A cleaved (100) surface was found to be initially unreactive even in 10-3M HCl. Subsequently dissolution develops and surface roughness increases until a steady state is reached. An equation describing the transition is presented. Dissolution experiments in the pH range 6.0-7.0 with deliberately roughened surfaces and with surfaces misoriented at a known angle to the (100) plane are described and the dissolution rates correlated with the surface morphology as revealed by electron microscopy. © 1986.
Publication status:
Published

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Publisher copy:
10.1016/0021-9797(86)90200-6

Authors

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author


Journal:
JOURNAL OF COLLOID AND INTERFACE SCIENCE More from this journal
Volume:
113
Issue:
1
Pages:
12-20
Publication date:
1986-09-01
DOI:
ISSN:
0021-9797


UUID:
uuid:01aedb0b-9859-4ca6-9023-0a375a744eef
Local pid:
pubs:42712
Source identifiers:
42712
Deposit date:
2012-12-19
ARK identifier:

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