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Bimodal growth of Au on SrTiO3 (001)

Abstract:
We have investigated the vapor phase growth of Au on SrTiO3 (001)-(2x1) substrates by UHV scanning tunneling microscopy. Submonolayer (ML) coverages below 300°C wet the surface as disordered metastable 2D islands. Beyond 0.75 ML fcc nanocrystals with a (111) interface are nucleated and ripen by dewetting the surrounding layer. Some multiply twinned fivefold symmetric clusters are also created. Above 400°C dewetting occurs for all coverages and the surface is only populated by nanocrystals and fivefold clusters. A planar ground state configuration for small Au clusters and a higher interface energy for crystals than for wetted 2D ML films explains these results.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1103/PhysRevLett.96.086104

Authors

More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Research group:
Castell Group: Surface Nanoscience
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Research group:
Castell Group: Surface Nanoscience
Role:
Author


Publisher:
American Physical Society
Journal:
Physical Review Letters More from this journal
Volume:
96
Issue:
8
Pages:
086104
Publication date:
2006-03-01
Edition:
Publisher's version
DOI:
EISSN:
1079-7114
ISSN:
0031-9007


Language:
English
Keywords:
Subjects:
UUID:
uuid:016d9289-305d-4e4c-bca3-a67d4c04a88d
Local pid:
ora:1000
Deposit date:
2008-03-14
ARK identifier:

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