Journal article icon

Journal article

Small molecule activation by frustrated Lewis pairs.

Abstract:

A series of frustrated Lewis pairs (FLPs) based on the Lewis acids tris(perchloroaryl)borane (BAr(Cl)), and tris(2,2',2''-perfluorobiphenyl)borane (PBB) and trialkylphosphines were prepared; their ability to effect the heterolytic cleavage of dihydrogen, insert carbon dioxide into the borohydride, and reduce the resulting formatoborate to methanol were studied. Additionally, the insertion of CO(2) into a B-OH bond is explored with the ultimate aim of developing a homogeneous, catalytic prepar...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1039/c2dt32525j

Authors


Expand authors...
Journal:
Dalton transactions (Cambridge, England : 2003)
Volume:
42
Issue:
7
Pages:
2431-2437
Publication date:
2013-02-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:00fa8522-f592-43f2-91e4-bd2e943bac7f
Source identifiers:
379909
Local pid:
pubs:379909

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP