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Synthesis, characterisation and structural studies of amidinate and guanidinate alkaline earth–transition metal bonded complexes

Abstract:

Reaction of magnesium amidinate complexes of the form [{MesC(NR)2}MgBr(OEt2)]2 (R = i Pr, Dipp, Mes) with the potassium salts of transition metal anions K[CpFe(CO)2] (K[Fp]) and K[Co(CO)3(PCy3)](THF)2 gave the complexes {MesC(NR)2}MgFp(THF) and {MesC(NR)2}Mg{Co(CO)3(PCy3)}(THF). Single crystal X-ray diffraction studies of {MesC(NR)2}Mg{Co(CO)3(PCy3)}(THF) for R = i Pr and Dipp confirm these to have Mg‒Co bonds in the solid state. Reaction of the structurally similar magnesium guanidinate comp...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1016/j.poly.2016.02.028

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Leverhulme Trust More from this funder
Publisher:
Elsevier Publisher's website
Journal:
Polyhedron Journal website
Volume:
116
Pages:
64–75
Publication date:
2016-03-26
Acceptance date:
2016-02-19
DOI:
EISSN:
1873-3719
ISSN:
0277-5387
URN:
uuid:00cab998-05e0-4577-bb60-2be0890384d7
Source identifiers:
607500
Local pid:
pubs:607500

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