- Abstract:
-
Abstraction of iodide from [Cp(CO)3MoI] (Cp = η5-C5H5) using the silver salt of the weakly coordinating anion [closo-CB11H11Br]-, initially affords an intermediate dimeric complex, [MoCp(CO)3I·Ag(CB11H11Br)]2, which has a central {AgI}2 core appended by two carborane anions in the solid state. Prolonged reaction does result in elimination of AgI to form [MoCp(CO)3(CB11 H11Br)], but not cleanly. This complex can be isolated in good yield by hydride abstraction from [Cp(CO)3MoH] using the new t...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/b303537a
-
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- Journal:
- DALTON TRANSACTIONS
- Issue:
- 14
- Pages:
- 2894-2904
- Publication date:
- 2003-01-01
- DOI:
- ISSN:
-
1477-9226
- URN:
-
uuid:005c8619-2952-4c5c-826c-ba07ef44c551
- Source identifiers:
-
51709
- Local pid:
- pubs:51709
- Language:
- English
- Copyright date:
- 2003
Journal article
Investigation of the synthesis of {Mo(eta(5)-C5H5)(CO)(3)}(+) fragments partnered with the monoanionic carboranes [closo-CB11H11Br](-), [closo-CB11H6Br6](-) and [closo-HCB11Me11](-) by silver salt metathesis and hydride abstraction
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