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Low-symmetry distortions in Extended Metal Atom Chains (EMACs): Origins and consequences for electron transport

Abstract:

The extended metal atoms chains (EMACs) constitute a diverse group of molecules differing in both length and identity of the constituent metal ions. They therefore present important challenges to our understanding of metal-metal bonding and its relationship to structural, magnetic and electron transport properties. In this review we summarise our current understanding of the origins of low-symmetry distortions in these chains and their impact on current flow through the molecule. We conclude ...

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Publisher copy:
10.1016/j.ccr.2012.05.025

Authors


Georgiev, VP More by this author
DeBrincat, D More by this author
McGrady, JE More by this author
Journal:
Coordination Chemistry Reviews
Volume:
257
Issue:
1
Pages:
187-195
Publication date:
2013
DOI:
ISSN:
0010-8545
URN:
uuid:0059f9fb-4aa8-4be6-b568-488abd2c28dd
Source identifiers:
368142
Local pid:
pubs:368142

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