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Particle-impact voltammetry: The reduction of hydrogen peroxide at silver nanoparticles impacting a carbon electrode

Abstract:
The complete, two-electron reduction of hydrogen peroxide at silver nanoparticles during collisions of the nanoparticles with an inert carbon electrode is reported. The current passed during each impact (average duration 13 ms) is shown to be quantitatively approximated to that of the diffusion-limited current at an isolated NP-sphere of radius R, thereby enabling the sizing of the nanoparticles, and providing insight into future physical models of the contact environment. © 2012 Elsevier B.V. All rights reserved.
Publication status:
Published

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Publisher copy:
10.1016/j.cplett.2012.02.031

Authors

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author


Journal:
CHEMICAL PHYSICS LETTERS More from this journal
Volume:
531
Pages:
94-97
Publication date:
2012-04-02
DOI:
ISSN:
0009-2614


Language:
English
UUID:
uuid:0052c3ea-431f-4563-be0f-5ef666d4aec7
Local pid:
pubs:321625
Source identifiers:
321625
Deposit date:
2012-12-19
ARK identifier:

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