Journal article
Probing the structure, conformation, and stereochemical exchange in a family of lanthanide complexes derived from tetrapyridyl-appended cyclen.
- Abstract:
-
A series of lanthanide complexes have been synthesized from 1,4,7,10-tetrakis(2-pyridylmethyl)-1,4,7,10-tetraazacyclododecane. Crystallographic studies indicate that, in the solid phase, all of the lanthanide ions are 9-coordinate and are bound to eight N atoms from the donor ligand, with the ninth site being filled by a counterion or solvent molecule. In solution, time-resolved luminescence studies indicate that the luminescence exhibits contributions from two species corresponding to the no...
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- Publication status:
- Published
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- Publisher copy:
- 10.1021/ic100447m
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Bibliographic Details
- Journal:
- Inorganic chemistry
- Volume:
- 49
- Issue:
- 17
- Pages:
- 7700-7709
- Publication date:
- 2010-09-01
- DOI:
- EISSN:
-
1520-510X
- ISSN:
-
0020-1669
- Source identifiers:
-
71132
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:71132
- UUID:
-
uuid:004d54d6-661f-4abe-a656-1db5a1d9c9ef
- Local pid:
- pubs:71132
- Deposit date:
- 2012-12-19
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- Copyright date:
- 2010
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