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Probing the structure, conformation, and stereochemical exchange in a family of lanthanide complexes derived from tetrapyridyl-appended cyclen.

Abstract:

A series of lanthanide complexes have been synthesized from 1,4,7,10-tetrakis(2-pyridylmethyl)-1,4,7,10-tetraazacyclododecane. Crystallographic studies indicate that, in the solid phase, all of the lanthanide ions are 9-coordinate and are bound to eight N atoms from the donor ligand, with the ninth site being filled by a counterion or solvent molecule. In solution, time-resolved luminescence studies indicate that the luminescence exhibits contributions from two species corresponding to the no...

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Publication status:
Published

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Publisher copy:
10.1021/ic100447m

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Journal:
Inorganic chemistry
Volume:
49
Issue:
17
Pages:
7700-7709
Publication date:
2010-09-01
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Source identifiers:
71132
Language:
English
Keywords:
Pubs id:
pubs:71132
UUID:
uuid:004d54d6-661f-4abe-a656-1db5a1d9c9ef
Local pid:
pubs:71132
Deposit date:
2012-12-19

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