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Triacetonide of Glucoheptonic Acid in the Scalable Syntheses of d-Gulose, 6-Deoxy-d-gulose, l-Glucose, 6-Deoxy-l-glucose, and Related Sugars.

Abstract:
Ease of separation of petrol-soluble acetonides derived from the triacetonide of methyl glucoheptonate allows scalable syntheses of rare sugars containing the l-gluco or d-gulo structural motif with any oxidation level at the C6 or C1 position of the hexose, usually without chromatography: meso-d-glycero-d-guloheptitol available in two steps is an ideal entry point for the study of the biotechnological production of heptoses.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acs.orglett.6b02041

Authors


More by this author
Institution:
University of Oxford
Division:
MSD
Department:
Biochemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MSD
Department:
Biochemistry
Role:
Author
Publisher:
American Chemical Society
Journal:
Organic Letters More from this journal
Volume:
18
Issue:
16
Pages:
4112-4115
Publication date:
2016-08-03
Acceptance date:
2016-08-02
DOI:
EISSN:
1523-7052
ISSN:
1523-7060
Pmid:
27487167
Language:
English
Keywords:
Pubs id:
pubs:638246
UUID:
uuid:f0e8ef12-a8cc-482d-abd3-1ecc24a4bed2
Local pid:
pubs:638246
Source identifiers:
638246
Deposit date:
2016-09-09

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