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Heteroditopic transition metal dithiocarbamate receptors for binding cation-anion ion pairs

Abstract:

New heteroditopic nickel(II) and copper(II) transition metal dithiocarbamate ion pair receptors that contain amide and crown ether recognition sites have been prepared via metal directed self-assembly. Preliminary coordination studies reveal that these systems bind group 1 metal cations and a variety of anions. With the ditopic nickel(II) receptor, bis benzo-15-crown-5 intramolecular sandwich complexation of potassium cation cooperatively enhances the recognition of acetate. Electrochemical i...

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Journal:
Journal of Supramolecular Chemistry
Volume:
2
Issue:
1-3
Pages:
89-92
Publication date:
2002-01-05
DOI:
ISSN:
1472-7862
URN:
uuid:feb1e0ea-04c9-4277-b794-05e1a298a4d5
Source identifiers:
324820
Local pid:
pubs:324820
Language:
English
Keywords:

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