- Abstract:
-
New heteroditopic nickel(II) and copper(II) transition metal dithiocarbamate ion pair receptors that contain amide and crown ether recognition sites have been prepared via metal directed self-assembly. Preliminary coordination studies reveal that these systems bind group 1 metal cations and a variety of anions. With the ditopic nickel(II) receptor, bis benzo-15-crown-5 intramolecular sandwich complexation of potassium cation cooperatively enhances the recognition of acetate. Electrochemical i...
Expand abstract - Publisher copy:
- 10.1016/S1472-7862(02)00083-7
-
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- Journal:
- Journal of Supramolecular Chemistry
- Volume:
- 2
- Issue:
- 1-3
- Pages:
- 89-92
- Publication date:
- 2002-01-05
- DOI:
- ISSN:
-
1472-7862
- URN:
-
uuid:feb1e0ea-04c9-4277-b794-05e1a298a4d5
- Source identifiers:
-
324820
- Local pid:
- pubs:324820
- Language:
- English
- Keywords:
- Copyright date:
- 2002
Journal article
Heteroditopic transition metal dithiocarbamate receptors for binding cation-anion ion pairs
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