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Electrodes modified with electroinactive layers: distinguishing through-film transport from pinhole (pore) diffusion.

Abstract:

Electrodes modified with layers, for example, of polymers or self-assembled monolayers, are of great importance from both the fundamental and applied points of view. Two different models of electrodes covered with electroinactive layers can be proposed. First, the electrode is covered with a uniform layer into which the electroactive species dissolves and then diffuses through, or second, the layer contains pinholes that are exclusively responsible for diffusional transport to the electrode. ...

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Publication status:
Published

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Publisher copy:
10.1021/la803488t

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
Langmuir : the ACS journal of surfaces and colloids
Volume:
25
Issue:
4
Pages:
2519-2529
Publication date:
2009-02-05
DOI:
EISSN:
1520-5827
ISSN:
0743-7463
URN:
uuid:fe8882c8-8b72-46fe-8675-3114c93a63cb
Source identifiers:
34596
Local pid:
pubs:34596
Language:
English

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