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Journal article

Two modifications of layered cobaltous terephthalate: Crystal structures and magnetic properties

Abstract:

The synthesis, characterization, crystal structure, and magnetic properties of Co2(OH)2BDC and Co(H2O)2BDC (BDC is benzene 1,4-dicarboxylate or terephthalate, O2CC6H4CO2) are reported. Co2(OH)2BDC (C2/m, a=19.952, b=3.286, c=6.295 Å, β=95.84°, Z=2, V=410.6 Å3) consists of two types of edge-sharing CoO6 chains that are connected to each other by OH (Co-O-Co bridges) to form layers that are further joined together through terephthalate. It exhibits unusual magnetic properties: above 48 K it dis...

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Publication status:
Published

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Publisher copy:
10.1006/jssc.2001.9163

Authors


Kumagai, H More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Materials
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Physics, Condensed Matter Physics
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Journal:
JOURNAL OF SOLID STATE CHEMISTRY
Volume:
159
Issue:
2
Pages:
343-351
Publication date:
2001-07-05
DOI:
ISSN:
0022-4596
URN:
uuid:fe280404-c02d-4817-b177-fae3b0345d8e
Source identifiers:
30211
Local pid:
pubs:30211
Language:
English

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