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New group 10 complexes of the bulky iminophosphine ligands [Ph2PCH2C(Ph)=N(2,6-R2C6H3)], where R = Me, Pr-i

Abstract:

New neutral and cationic complexes [NiBr2(L1)] (1), [NiBr 2(OPHPh2)(L1)] (2), [NiMe2(L1)] (3), [NiBr(PMe3)(L1)](Br) (4), [Ni(CH3CN)(PMe 3)(L1)](BF4)2 (5), [PdBr2(L1)] (6), [PdI2(L1)] (7), [PtMeCl(L1)] (8), [PtMe2(L1)] (9), [Pt(CH3CN)2(L1)](BF4)2 (10), [Pt(L1)2](X)2 [X = Cl (11a), Br (11b)], [PtX(L1) 2](X) [X = Cl (12a), Br (12b)], where L1: [Ph2PCH 2C(Ph)=N(2,6-Me2C6H3)2] and L2: [Ph2PCH2C(Ph)= N(2,6-iPr 2C6H3)2], have been prepared and characterised. The molecular structures of 1, 2, 6, 7 an...

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Publication status:
Published

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Publisher copy:
10.1039/b412391c

Authors


Coleman, KS More by this author
Cowley, AR More by this author
Green, MLH More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
NEW JOURNAL OF CHEMISTRY
Volume:
29
Issue:
2
Pages:
385-397
Publication date:
2005
DOI:
EISSN:
1369-9261
ISSN:
1144-0546
URN:
uuid:fde4db36-1ff2-425a-982c-644ab554cb6e
Source identifiers:
104463
Local pid:
pubs:104463
Language:
English

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