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APPLICATION OF SCALING THEORY TO VIBRATIONAL-RELAXATION IN LINEAR ANHARMONIC TRIATOMIC-MOLECULES

Abstract:

The energy-corrected-sudden (ECS) scaling theory is extended to vibrational relaxation in the collisions of anharmonic linear triatomic molecules with atoms. Application is made to the collisions of He atoms with 12C 16O2, 14C 16O2, and 12C 18O2. By combining the rate constants for the (0110→00°0) transitions, calculated using the vibrational close-coupling rotational infinite-order-sudden (VCC-IOS) method, with the ECS scaling theory, we predict rate constants for the transitions (10°0→0110)...

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Publication status:
Published

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Publisher copy:
10.1063/1.446069

Authors


DEPRISTO, A More by this author
Journal:
JOURNAL OF CHEMICAL PHYSICS
Volume:
79
Issue:
5
Pages:
2206-2211
Publication date:
1983
DOI:
ISSN:
0021-9606
URN:
uuid:fdb305f9-623e-427b-933a-779b8e739fc5
Source identifiers:
52938
Local pid:
pubs:52938
Language:
English

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