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APPLICATION OF SCALING THEORY TO VIBRATIONAL-RELAXATION IN LINEAR ANHARMONIC TRIATOMIC-MOLECULES

Abstract:

The energy-corrected-sudden (ECS) scaling theory is extended to vibrational relaxation in the collisions of anharmonic linear triatomic molecules with atoms. Application is made to the collisions of He atoms with 12C 16O2, 14C 16O2, and 12C 18O2. By combining the rate constants for the (0110→00°0) transitions, calculated using the vibrational close-coupling rotational infinite-order-sudden (VCC-IOS) method, with the ECS scaling theory, we predict rate constants for the transitions (10°0→0110)...

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Publication status:
Published

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Publisher copy:
10.1063/1.446069
Journal:
JOURNAL OF CHEMICAL PHYSICS More from this journal
Volume:
79
Issue:
5
Pages:
2206-2211
Publication date:
1983-01-01
DOI:
ISSN:
0021-9606
Language:
English
Pubs id:
pubs:52938
UUID:
uuid:fdb305f9-623e-427b-933a-779b8e739fc5
Local pid:
pubs:52938
Source identifiers:
52938
Deposit date:
2013-11-17

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