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TOF-2: a large 1D channel thorium organic framework.

Abstract:
A new neutral 1D channel thorium organic framework material (TOF-2) has been synthesized under hydrothermal conditions. TOF-2 exhibits a hexagonal channel structure consisting of eight-coordinate ThO6F2 polyhedra and 1,3,5-benzentricarboxylate ligands. The channels run along the c-axis and are approximately 13 A in diameter. The single-crystal X-ray structure suggests that the amount of void space is 41%. The structure is stable to ca. 400 degrees C. Gas adsorption measurements show deferential gas uptake behavior.
Publication status:
Published

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Publisher copy:
10.1021/ja800395q

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Journal of the American Chemical Society
Volume:
130
Issue:
12
Pages:
3762-3763
Publication date:
2008-03-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:fd8ce09b-37c3-4a1c-b754-29c856a9fd20
Source identifiers:
51270
Local pid:
pubs:51270
Language:
English

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