Journal article icon

Journal article

Single-molecule magnet properties of a monometallic dysprosium pentalene complex

Abstract:
The pentalene-ligated dysprosium complex [(η8-Pn†)Dy(Cp*)] (1Dy) (Pn† = [1,4-(iPr3Si)2C8H4]2-) and its magnetically dilute analogue are single-molecule magnets, with energy barriers of 245 cm-1. Whilst the [Cp*]- ligand in 1Dy provides a strong axial crystal field, the overall axiality of this system is attenuated by the unusual folded structure of the [Pn†]2- ligand.
Publication status:
Published
Peer review status:
Peer reviewed

Actions


Access Document


Files:
Publisher copy:
10.1039/c8cc03516d

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
ORCID:
0000-0002-2108-2709
More by this author
Role:
Author
ORCID:
0000-0001-7190-4160
More by this author
Role:
Author
ORCID:
0000-0001-6067-5171
More by this author
Role:
Author
ORCID:
0000-0003-0401-4373
More by this author
Role:
Author
ORCID:
0000-0002-6020-0309
Expand authors...
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Chemical Communications Journal website
Volume:
54
Issue:
51
Pages:
7085-7088
Publication date:
2018-06-07
Acceptance date:
2018-05-28
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Pmid:
29878012
Source identifiers:
857518
Language:
English
Keywords:
Pubs id:
pubs:857518
UUID:
uuid:fd8694ac-494f-4829-b8a2-f0e585f5c843
Local pid:
pubs:857518
Deposit date:
2018-06-18

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP