Journal article
Single-molecule magnet properties of a monometallic dysprosium pentalene complex
- Abstract:
- The pentalene-ligated dysprosium complex [(η8-Pn†)Dy(Cp*)] (1Dy) (Pn† = [1,4-(iPr3Si)2C8H4]2-) and its magnetically dilute analogue are single-molecule magnets, with energy barriers of 245 cm-1. Whilst the [Cp*]- ligand in 1Dy provides a strong axial crystal field, the overall axiality of this system is attenuated by the unusual folded structure of the [Pn†]2- ligand.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
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(Accepted manuscript, pdf, 1.4MB)
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- Publisher copy:
- 10.1039/c8cc03516d
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Authors
Funding
Bibliographic Details
- Publisher:
- Royal Society of Chemistry Publisher's website
- Journal:
- Chemical Communications Journal website
- Volume:
- 54
- Issue:
- 51
- Pages:
- 7085-7088
- Publication date:
- 2018-06-07
- Acceptance date:
- 2018-05-28
- DOI:
- EISSN:
-
1364-548X
- ISSN:
-
1359-7345
- Pmid:
-
29878012
- Source identifiers:
-
857518
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:857518
- UUID:
-
uuid:fd8694ac-494f-4829-b8a2-f0e585f5c843
- Local pid:
- pubs:857518
- Deposit date:
- 2018-06-18
Terms of use
- Copyright holder:
- Kilpatrick etal
- Copyright date:
- 2018
- Notes:
-
Copyright © 2018 the Authors. This is the accepted manuscript version of the article. The final version is available online from the
Royal Society of Chemistry at: https://doi.org/10.1039/c8cc03516d
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