- Abstract:
-
The synthesis of the Mn(II) phase 4H-Ba(0.5)Sr(0.5)MnO(2+delta) via the topotactic reduction of 4H-Ba(0.5)Sr(0.5)MnO(3-x) with the novel reducing agent LiH, is described. Neutron powder diffraction data show that oxide ions are deintercalated from the host structure in a disordered manner to yield "tetrahedral" MnO(4) coordination sites. Magnetic susceptibility and neutron powder diffraction data show that the title phase adopts a canted antiferromagnetically ordered state below T(N) = 355K, ...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ic801185z
-
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- Journal:
- Inorganic chemistry
- Volume:
- 47
- Issue:
- 23
- Pages:
- 10959-10964
- Publication date:
- 2008-12-05
- DOI:
- EISSN:
-
1520-510X
- ISSN:
-
0020-1669
- URN:
-
uuid:fd7963d5-d68a-4cde-8575-de9122bfec5e
- Source identifiers:
-
34444
- Local pid:
- pubs:34444
- Language:
- English
- Copyright date:
- 2008
Journal article
Room temperature antiferromagnetic order in the Mn(II) Oxide 4H-Ba(0.5)Sr(0.5)MnO(2+delta).
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