Journal article

FORMATION OF 3-VERTEX METALLABORANES FROM MONOBORANE PRECURSORS - X-RAY CRYSTAL-STRUCTURES OF THE MOLYBDENUM AND RUTHENIUM COMPLEXES [MO(ETA-C5H5)2H(ETA-2-B2H5)] AND [RU(ETA-C5ME5)(PME3)(ETA-2-B2H7)]

Abstract:: The novel three-vertex metallaborane [Ru(η-C5Me 5)(PMe3)(η2-B2H7)] (1) has been synthesised by reaction of [Ru(η-C5Me 5)(PMe3)Cl2] with NaBH4; homologation is also observed in the reaction of [Mo(η-C5H 5)2H2] with BH3·THF, which forms [Mo(η-C5H5)2H(η2- B2H5)] (2); X-ray crystal structures of compounds (1) and (2) are reported.

Publication status:: Published

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APA Style

Grebenik, P., Green, M., Kelland, M., Leach, J., Mountford, P., Stringer, G., Walker, N., & Wong, L. (1988). FORMATION OF 3-VERTEX METALLABORANES FROM MONOBORANE PRECURSORS - X-RAY CRYSTAL-STRUCTURES OF THE MOLYBDENUM AND RUTHENIUM COMPLEXES [MO(ETA-C5H5)2H(ETA-2-B2H5)] AND [RU(ETA-C5ME5)(PME3)(ETA-2-B2H7)]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 12, 799–801.

MLA Style

Grebenik, P., et al. “FORMATION OF 3-VERTEX METALLABORANES FROM MONOBORANE PRECURSORS - X-RAY CRYSTAL-STRUCTURES OF THE MOLYBDENUM AND RUTHENIUM COMPLEXES [MO(ETA-C5H5)2H(ETA-2-B2H5)] AND [RU(ETA-C5ME5)(PME3)(ETA-2-B2H7)].” JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, no. 12, 1988, pp. 799–801.

Chicago Style

Grebenik, P, M Green, M Kelland, J Leach, P Mountford, G Stringer, N Walker, and L Wong. 1988. “FORMATION OF 3-VERTEX METALLABORANES FROM MONOBORANE PRECURSORS - X-RAY CRYSTAL-STRUCTURES OF THE MOLYBDENUM AND RUTHENIUM COMPLEXES [MO(ETA-C5H5)2H(ETA-2-B2H5)] AND [RU(ETA-C5ME5)(PME3)(ETA-2-B2H7)].” JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, no. 12: 799–801.
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Publisher copy:: 10.1039/c39880000799

Authors

+ Grebenik, P More by this author

Role:: Author

+ Green, M More by this author

Role:: Author

+ Kelland, M More by this author

Role:: Author

+ Leach, J More by this author

Role:: Author

+ Mountford, P More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

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Journal:: JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS More from this journal
Issue:: 12
Pages:: 799-801
Publication date:: 1988-06-15
DOI:: 10.1039/c39880000799
ISSN:: 0022-4936

Language:: English
Pubs id:: pubs:42878
UUID:: uuid:fd6b7d77-8e90-4e24-a396-0fb3036beac9
Local pid:: pubs:42878
Source identifiers:: 42878
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 1988

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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