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A General Synthesis of Phosphorus‐ and Arsenic‐Containing Analogues of the Thio‐ and Seleno‐cyanate Anions

Abstract:
A general synthetic protocol for the synthesis of phosphorus- and arsenic-containing analogues of the thio- and seleno-cyanate anions is reported. This procedure allows for the isolation of three unprecedented species: the phosphaethynselenolate, PCSe– (1), the arsaethynthiolate, AsCS– (2), and the arsaethynselenolate, AsCSe– (3), anions. The structures, electronic properties, and spectroscopic signatures of these species are reported.
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1002/anie.201805348

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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Oxford college:
Lady Margaret Hall
ORCID:
0000-0002-7311-1663
Publisher:
Wiley Publisher's website
Journal:
Angewandte Chemie Journal website
Volume:
58
Issue:
26
Pages:
8230-8234
Publication date:
2018-05-22
Acceptance date:
2018-05-22
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Pubs id:
pubs:854523
URN:
uri:fd2b4f6b-30af-423a-a0b7-04fdb95480a5
UUID:
uuid:fd2b4f6b-30af-423a-a0b7-04fdb95480a5
Local pid:
pubs:854523

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