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Reactions of (BuC)-Bu-t P with cyclooctatetraene-supported titanium imido complexes

Abstract:

Reaction of the pseudo two-coordinate titanium imido complexes [Ti(N tBu)(COT)] (1; COT = η8-C8H8) and [Ti(NtBu)(COT″)] (2; COT″ = η 8-1,4-C8H6(SiMe3)2) with 2 equiv of tBuC≡P generated the new complexes [Ti{N( tBu)PC(tBu)PC(tBu)}(COT)] (4) and [Ti{N( tBu)PC(tBu)PC(tBu)}(COT″)] (5), respectively. Complex 4 was crystallographically characterized, and a density functional theory (DFT) study combined with photoelectron (PE) spectroscopy revealed this apparently 20-valence-electron species to con...

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Publication status:
Published

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Publisher copy:
10.1021/om060273o

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
ORGANOMETALLICS More from this journal
Volume:
25
Issue:
15
Pages:
3688-3700
Publication date:
2006-07-17
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
Language:
English
Pubs id:
pubs:40032
UUID:
uuid:fd217227-c8bc-4e5f-ab04-81059893289e
Local pid:
pubs:40032
Source identifiers:
40032
Deposit date:
2012-12-19

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