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A zero-field electron spin resonance spectrometer for the study of transient radical ion pairs

Abstract:

A zero-field electron spin resonance spectrometer is described for measuring the spectra of spin-correlated radical ion pairs in solution in the frequency range 1-80 MHz. The radical ions are created by continuous optical irradiation and rapidly recombine to form an exciplex whose fluorescence is monitored as the radiofrequency is swept, also continuously. The probability of recombination depends upon the singlet character of the radical pair at the time that the radicals re-encounter after a...

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Publication status:
Published

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Publisher copy:
10.1088/0957-0233/12/5/311

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
MEASUREMENT SCIENCE and TECHNOLOGY
Volume:
12
Issue:
5
Pages:
635-643
Publication date:
2001-05-05
DOI:
EISSN:
1361-6501
ISSN:
0957-0233
URN:
uuid:fcd6b2aa-48d9-495b-852d-38b8a0080d2b
Source identifiers:
37865
Local pid:
pubs:37865

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