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Journal article

Dehydrogenative boron homocoupling of an amine-borane.

Abstract:
A meeting of borons: The homocoupling of a B-B bond in an amine-borane is reported to give a diborane coordinated to a RhI metal center (see picture; C gray/black, O red, P blue, B green, N orange). The pathway for the occurrence of this reaction was also studied using density functional theory to calculate the free energies of each intermediate. Copyright © 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
Publication status:
Published

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Publisher copy:
10.1002/anie.201304382

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Angewandte Chemie (International ed. in English) More from this journal
Volume:
52
Issue:
37
Pages:
9776-9780
Publication date:
2013-09-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Language:
English
Keywords:
Pubs id:
pubs:414684
UUID:
uuid:fccd6551-cef5-40a5-8ffa-ac5a04e08abe
Local pid:
pubs:414684
Source identifiers:
414684
Deposit date:
2013-11-17

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