- Abstract:
-
The technique of Doppler-resolved laser-induced fluorescence spectroscopy has been employed to study the scalar and vector properties of fragments generated via photodissociation of two large polyatomic molecules, tert-butyl nitrite excited into its S2 state at 250 nm and tert-butyl hydroperoxide photolyzed at 248 nm into its first absorption continuum. Experiments on the former system confirm the planar nature of the dissociation, which generates NO fragments with vNO ⊥ JNO, and the A′ symme...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/j100330a030
-
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- Journal:
- JOURNAL OF PHYSICAL CHEMISTRY
- Volume:
- 92
- Issue:
- 19
- Pages:
- 5485-5491
- Publication date:
- 1988-09-22
- DOI:
- EISSN:
-
1541-5740
- ISSN:
-
0022-3654
- URN:
-
uuid:fcb3c3b4-8396-4012-82ca-d11f1e02b41a
- Source identifiers:
-
52545
- Local pid:
- pubs:52545
- Language:
- English
- Copyright date:
- 1988
Journal article
PHOTODISSOCIATION DYNAMICS OF TERT-BUTYL NITRITE (S-2) AND TERT-BUTYL HYDROPEROXIDE AT 248-250 NM
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