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PHOTODISSOCIATION DYNAMICS OF TERT-BUTYL NITRITE (S-2) AND TERT-BUTYL HYDROPEROXIDE AT 248-250 NM

Abstract:

The technique of Doppler-resolved laser-induced fluorescence spectroscopy has been employed to study the scalar and vector properties of fragments generated via photodissociation of two large polyatomic molecules, tert-butyl nitrite excited into its S2 state at 250 nm and tert-butyl hydroperoxide photolyzed at 248 nm into its first absorption continuum. Experiments on the former system confirm the planar nature of the dissociation, which generates NO fragments with vNO ⊥ JNO, and the A′ symme...

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Publication status:
Published

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Publisher copy:
10.1021/j100330a030

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
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Journal:
JOURNAL OF PHYSICAL CHEMISTRY
Volume:
92
Issue:
19
Pages:
5485-5491
Publication date:
1988-09-22
DOI:
EISSN:
1541-5740
ISSN:
0022-3654
URN:
uuid:fcb3c3b4-8396-4012-82ca-d11f1e02b41a
Source identifiers:
52545
Local pid:
pubs:52545
Language:
English

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