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'Covalent' effects in 'ionic' liquids

Abstract:

Many binary systems (and their mixtures) which might be expected to be 'ionic', from electronegativity considerations, are found to exhibit pronounced 'covalent effects' in their condensed-phase structure and dynamical properties. Recent work, involving both electronic structure calculations and computer simulation, has suggested that the interactions arise and are describable within the ionic model - provided that many-body effects, whose origin is the change in an ion's properties caused by...

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Publication status:
Published

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Authors


Madden, PA More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Volume:
12
Issue:
8A
Pages:
A95-A108
Publication date:
2000-02-28
ISSN:
0953-8984
URN:
uuid:fc04c4f8-612c-48d3-ab46-2114a9849ef7
Source identifiers:
60148
Local pid:
pubs:60148

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