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A polycyclic borazine radical cation: [1,2-B2{1,2-(MeN)2C6H4}2]˙(+).

Abstract:
The radical cation [1,2-B2{1,2-(MeN)2C6H4}2]˙(+) has been synthesised and its structure and bonding have been probed using a combination of X-ray crystallography, EPR spectroscopy and DFT calculations which show that it represents a new type of radical centred primarily on two N-heterocyclic units joined by a B2 linker but with only a minor contribution from boron-based orbitals.
Publication status:
Published

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Publisher copy:
10.1039/c3cc44990d

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Journal:
Chemical Communications More from this journal
Volume:
49
Issue:
88
Pages:
10364-10366
Publication date:
2013-11-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Language:
English
Keywords:
Pubs id:
pubs:436674
UUID:
uuid:fbe13a92-5401-44e8-a990-a7300d82cb52
Local pid:
pubs:436674
Source identifiers:
436674
Deposit date:
2013-11-16

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