- The palladium-catalyzed hydrophosphonylation of alkenes with previously unreactive acyclic dialkyl H-phosphonates has been developed. A catalyst system based on palladium/DavePhos or palladium/SPhos enables the transformation of various alkenes to phosphonates in moderate to good yields and with excellent levels of regioselectivity. Hydrophosphonylations with internal, disubstituted and/or unactivated alkenes are also reported. © 2014 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
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Palladium-Catalyzed Hydrophosphonylation of Alkenes with Dialkyl H-Phosphonates
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