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Palladium-Catalyzed Hydrophosphonylation of Alkenes with Dialkyl H-Phosphonates

Abstract:
The palladium-catalyzed hydrophosphonylation of alkenes with previously unreactive acyclic dialkyl H-phosphonates has been developed. A catalyst system based on palladium/DavePhos or palladium/SPhos enables the transformation of various alkenes to phosphonates in moderate to good yields and with excellent levels of regioselectivity. Hydrophosphonylations with internal, disubstituted and/or unactivated alkenes are also reported. © 2014 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
Publication status:
Published

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Publisher copy:
10.1002/adsc.201400190

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
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Journal:
ADVANCED SYNTHESIS and CATALYSIS
Volume:
356
Issue:
11-12
Pages:
2703-2708
Publication date:
2014-08-11
DOI:
EISSN:
1615-4169
ISSN:
1615-4150
Source identifiers:
474049
Language:
English
Keywords:
Pubs id:
pubs:474049
UUID:
uuid:fbddbe63-65cf-4cef-ba5e-c6ccdd1b9ae8
Local pid:
pubs:474049
Deposit date:
2014-07-11

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