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Electroreduction of oxygen in a series of room temperature ionic liquids composed of group 15-centered cations and anions

Abstract:

The electrochemical reduction of oxygen is reported in four room temperature ionic liquids (RTILs) based on quaternary alkyl -onium cations and heavily fluorinated anions in which the central atom is either nitrogen or phosphorus. Data were collected using cyclic voltammetry and potential step chronoamperometry at gold, platinum, and glassy carbon disk electrodes of micrometer dimension under water-free conditions at a controlled temperature. Analysis via fitting to appropriate theoretical eq...

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Publication status:
Published

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Publisher copy:
10.1021/jp031309i

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY B More from this journal
Volume:
108
Issue:
23
Pages:
7878-7886
Publication date:
2004-06-10
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
Language:
English
Pubs id:
pubs:39088
UUID:
uuid:fbcd9dda-32a9-464a-ba91-efdd2a5def65
Local pid:
pubs:39088
Source identifiers:
39088
Deposit date:
2012-12-19

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