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Pentalene complexes of group 7 metal carbonyls: an organometallic mixed-valence system with very large metal-metal electronic coupling.

Abstract:

The bimetallic complexes [M(CO)(3)](2)(mu:eta(5):eta(5)-Pn) (Pn = pentalene, C(8)H(6); M = Mn, Re) have been synthesized and characterized crystallographically; the Mn compound was isolated as solely the anti-isomer, while the Re analogue was formed as a mixture of anti- and syn-isomers. [Mn(CO)(3)](2)(mu:eta(5):eta(5)-Pn) may be reduced chemically to its mono- and dianions; the mixed-valence Mn(I)/Mn(0) monoanion is shown by ESR, vibrational, and electronic spectroscopies to be a Robin-Day c...

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Publication status:
Published

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Publisher copy:
10.1021/ja027705g

Authors


Hascall, T More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Journal of the American Chemical Society
Volume:
124
Issue:
39
Pages:
11610-11611
Publication date:
2002-10-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:fbc1e460-374b-4b21-9419-79004c270f6d
Source identifiers:
51223
Local pid:
pubs:51223
Language:
English

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